Technological conditions of diffusive boride coating formation on silicon carbide and molybdenum disilicide https://doi.org/10.33108/visnyk_tntu2018.02.087

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Vasiliy Kovbashyn
Igor Bochar

Abstract

Basic directions of the diffusive boride coating formation on reaction-sintered silicon carbide and molybdenum disilicide are described. Technological conditions of non-metal ceramic materials boriding depending on the consideration of the amorphous boron concentration in the powder mixture are investigated and
analyzed. It is determined that it is possible to speed up the rate of saturation process of the silicon carbide and molybdenum disilicide with boron by introducing sodium and aluminum fluorides as activating agents. Based on the carried out researches, optimal conditions for choosing the concentration of activating agents providing high saturation speed and improve operational parameters of the products are offered. It is also defined that to stimulate the process of boriding reaction-sintered ceramic materials, titanium hydride should be introduced into the saturated environment as the activating agent. Diffusion saturation of metals and alloys in hydrogen environment provides high saturation rate and good quality of the treated surface. The results of the carried out investigations prove that the saturation ability of the boride mixture increases significantly by introducing sodium
fluoride and titanium hydride into it.

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References

1. Kovbashyn V.I., Bochar I.Y. Vplyv tekhnolohiyi sylikoboruvannya keramichnykh materialiv na vlastyvosti zakhysnykh pokryttiv, Visnyk Ternopil's'koho natsional'noho tekhnichnoho universytetu. Ternopil', vol.78, no. 2, 2015. P. 130 – 138 [In Ukrainian].

2. Dzyadykevich Yu.V., Kislyj P.S., Bochar I.Y. Sposob obrabotki karbidokremnievyh nagrevatelej, Otkrytiya. Izobreteniya, no. 44, 1991. P. 286 [In Russian].

3. Hepworth M.A. Processing, Properties and Applications of Structural Silicon Carbides, Brit. Ceram. Proc., no 46, 2001. Р.113 – 125.

4. Kovbashyn V.I., Bochar I.Y. Tekhnolohichni osoblyvosti formuvannya sylitsydnoho pokryttya na karbidi kremniyu ta dysylitsydi molibdenu, Visnyk Ternopil's'koho natsional'noho tekhnichnoho universytetu, Ternopil'. Vol. 75, no. 3, 2014. P. 127 – 131 [In Ukrainian].

5. Kovbashyn V.I., Bochar I.Y. Perspective directions to increase heat tolerance of silicone carbid and molybdenum disilicide based materials, Visnyk Ternopil's'koho natsional'noho tekhnichnoho universytetu, Ternopil'. Vol. 82, no. 2, 2016. P. 49 – 551 [In Ukrainian].

6. Kovbashyn V.I., Bochar I.Y. Tekhnolohichni osoblyvosti formuvannya sylitsydnoho pokryttya na karbidi kremniyu ta dysylitsydi molibdenu, Visnyk Ternopil's'koho natsional'noho tekhnichnoho universytetu, Ternopil'. Vol. 86, no. 2, 2017. P. 14 – 20. [In Ukrainian].